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Sometimes less is more

Nature Chem.: RUB researchers unmask Janus-faced nature of mechanical forces with the Jülich supercomputer. Reaction speed does not always increase in proportion to the applied force.

The harder you pull, the quicker it goes. At least, that used to be the rule in mechanochemistry, a method that researchers apply to set chemical reactions in motion by means of mechanical forces. However, as chemists led by Professor Dominik Marx, Chair of Theoretical Chemistry at the Ruhr-Universität Bochum now report in the journal “Nature Chemistry”, more force cannot in fact be translated one to one into a faster reaction. With complex molecular dynamic simulations on the Jülich supercomputer “JUQUEEN” they unmasked the Janus-faced nature of mechanochemistry. Up to a certain force, the reaction rate increases in proportion to the force. If this threshold is exceeded, greater mechanical forces speed up the reaction to a much lesser extent.

 

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