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COVER PICTURE: Theoretical Terahertz Spectroscopy of Free Radical Solutes in Solution: An EPR spin probe in water
Phys. Chem. Chem. Phys. : RESOLV member Prof. Dominik Marx presents terahertz (THz) spectroscopy methods to study the solvation dynamics of open-shell molecular radicals in water. Focusing on the nitroxide spin probe HMI (2,2,3,4,5,5-HexaMethylImidazolidin-1-oxyl), the study generalizes established spectral decomposition techniques—supermolecular solvation complex (SSC) and cross-correlation…