Angew. Chem. Int. Ed. : With RESOLV support, Prof. M. Hansmann and his team identified the strongest neutral nucleophiles to date—mesoionic olefins—topping the Mayr scale and opening new paths in catalysis
Angew. Chem. Int. Ed. : RESOLV members, Prof. Christian Merten and Prof. Lukas J. Gooßen present a new Pd-catalyzed Schöllkopf-type amino acid synthesis that enables direct conversion of abundant aryl chlorides into valuable arylglycines. Using methylnaphthyl(XPhos)-Pd catalyst, ZnCl₂, and a strong lithium base, the reaction proceeds at room temperature with up to 95% yield and excellent…
ChemSusChem: RESOLV PI, Prof. K. Tschulik, showed how aqueous electrolytes, aldehydes exist in three forms: The non-hydrated aldehyde, the diol, and the diolate. This studi highlights that all three species exhibit electroactivity. Hence, it is possible to formulate approaches for addressing the OH−-induced decomposition of aldehydes during the electrochemical oxidation of aldehydes.
Nat. Commun.: RESOLV PI's, Prof. K. Morgenstern, Prof. W. Sander and Prof. E. Sanchez-Garcia, in collaborative cooperation, show how to alter the chirality dynamics of a single molecule through tip-induced van der Waals interactions.
J. Org. Chem.: Two structurally related isomeric benzazirines show very different tunneling behaviors which demonstrate the influence of position isomerism on quantum tunneling rates.
J. Am. Chem. Soc.: A novel surface-confined C–C coupling reaction studied by scanning tunneling microscopy in real space. Two carbene molecules and a water molecule generate Carbene fluorenylidene on a silver surface. 3 RESOLV groups pooled their expertise to find this coupling reaction, which is unprecedented in solution chemistry.
Chem. Rev.: RESOLV member, Prof. Marialore Sulpizi co authored a major interdisciplinary review article charting two decades worth of breakthroughs in understanding mineral-water interfaces, crucial to multiple processes such as energy storage and environmental remediation. The study highlights how cutting-edge experimental and computational advances are reshaping our view of interfacial chemistry…
Angew. Chem. Int. Ed.: Single-walled carbon nanotubes (SWCNTs) are used as fluorescent probes/sensors for biomolecules in the near infrared (NIR) tissue transparency window.