Highlight Publications


04
Oct 2023
  • News
  • Paper

Strong carbon nucleophiles

Angew. Chem. Int. Ed. : With RESOLV support, Prof. M. Hansmann and his team identified the strongest neutral nucleophiles to date—mesoionic olefins—topping the Mayr scale and opening new paths in catalysis

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02
Oct 2023
  • Press Releases
  • Paper

Water makes all the difference

Water is a major driving force in the formation of separate reaction compartments within cells.

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06
Sep 2023
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  • Paper

COVER PICTURE: Enantioselective Synthesis of Arylglycines via Pd-Catalyzed Couling of Schoellkopf Bis-Lactin Ethers with Aryl Chlorides

Angew. Chem. Int. Ed. : RESOLV members, Prof. Christian Merten and Prof. Lukas J. Gooßen present a new Pd-catalyzed Schöllkopf-type amino acid synthesis that enables direct conversion of abundant aryl chlorides into valuable arylglycines. Using methylnaphthyl(XPhos)-Pd catalyst, ZnCl₂, and a strong lithium base, the reaction proceeds at room temperature with up to 95% yield and excellent…

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15
Aug 2023
  • News
  • Paper

Cover Picture: Electrochemical Aldehyde Oxidation at Gold Electrodes: gem-Diol, non-Hydrated Aldehyde, and Diolate as Electroactive Species

ChemSusChem: RESOLV PI, Prof. K. Tschulik, showed how aqueous electrolytes, aldehydes exist in three forms: The non-hydrated aldehyde, the diol, and the diolate. This studi highlights that all three species exhibit electroactivity. Hence, it is possible to formulate approaches for addressing the OH−-induced decomposition of aldehydes during the electrochemical oxidation of aldehydes.

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08
Aug 2023
  • News
  • Paper

Featured in Nature Communications - Editorial Highlights

Nat. Commun.: RESOLV PI's, Prof. K. Morgenstern, Prof. W. Sander and Prof. E. Sanchez-Garcia, in collaborative cooperation, show how to alter the chirality dynamics of a single molecule through tip-induced van der Waals interactions.

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21
Jul 2023
  • Press Releases
  • Paper

Detection of bacteria and viruses with fluorescent nanotubes

J. Am. Chem. Soc: The new sensor design resembles a molecular toolbox that can be used to quickly assemble sensors for a variety of purposes.

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19
May 2023
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  • Paper

Cover Picture: Isomer-Specific Heavy-Atom Tunneling in the Ring Expansion of Fluorenylazirines

J. Org. Chem.: Two structurally related isomeric benzazirines show very different tunneling behaviors which demonstrate the influence of position isomerism on quantum tunneling rates.

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19
May 2023
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  • Paper

Water Molecules Enable Novel C–C Coupling Reactions on Surfaces

J. Am. Chem. Soc.: A novel surface-confined C–C coupling reaction studied by scanning tunneling microscopy in real space. Two carbene molecules and a water molecule generate Carbene fluorenylidene on a silver surface. 3 RESOLV groups pooled their expertise to find this coupling reaction, which is unprecedented in solution chemistry.

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15
May 2023
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  • Paper

COVER PICTURE: Oxide- and Silicate- Water interfaces and Their Roles in Technology and the Environment

Chem. Rev.: RESOLV member, Prof. Marialore Sulpizi co authored a major interdisciplinary review article charting two decades worth of breakthroughs in understanding mineral-water interfaces, crucial to multiple processes such as energy storage and environmental remediation. The study highlights how cutting-edge experimental and computational advances are reshaping our view of interfacial chemistry…

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09
May 2023
  • News
  • Paper

Cover Picture: Near-Infrared Fluorescence Lifetime Imaging of Biomolecules with Carbon Nanotubes

Angew. Chem. Int. Ed.: Single-walled carbon nanotubes (SWCNTs) are used as fluorescent probes/sensors for biomolecules in the near infrared (NIR) tissue transparency window.

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